Charge Mix Calculator

Charge mix calculation is the process of determining the optimal combination of raw materials—like scrap, pig iron, sponge iron, and ferroalloys—to be charged into the furnace. The goal is to achieve the desired chemical composition of the molten steel while minimizing cost and energy consumption.
Charge mix calculation is the unsung hero of steelmaking—where metallurgy meets economics. Whether you’re running an induction furnace or an electric arc furnace, mastering this step means better steel, lower costs, and a smarter melt shop.


Steelmaking Charge Mix Calculator

⚙️ Steelmaking Charge Mix Calculator

Calculate metallurgical compositions, yields, and production costs with Mr. Prashant Goswami

🔧 Charge Materials

Material% in ChargeYield %Cost ₹/tonC%Mn%Si%P%S%
🟤 Sponge Iron
⚫ Pig Iron
♻️ Scrap
🔹 SiMn
🔸 FeMn

⚡ Power Costs

💰 Other Costs

Includes refractories, electrodes, etc.

📚 Metallurgical Guides & Best Practices

🧪 Target Chemistry Guidelines

Carbon (C)
  • Low Carbon Steel: 0.05-0.25% (Structural, automotive)
  • Medium Carbon: 0.25-0.60% (Machinery, tools)
  • High Carbon: 0.60-1.70% (Springs, cutting tools)
  • Decarburization: ~0.15-0.25% loss during refining
Manganese (Mn)
  • Minimum: 0.30% for deoxidation
  • Typical Range: 0.60-1.65%
  • Function: Deoxidizer, hardenability, strength
  • Mn/S Ratio: Maintain >20:1 for hot workability
Silicon (Si)
  • Killed Steel: 0.15-0.35%
  • Semi-killed: 0.05-0.15%
  • Function: Primary deoxidizer, fluidity
  • High Si Steel: 0.50-2.00% (electrical grades)

⚠️ Impurity Control Limits

Phosphorus (P)
  • Maximum: 0.045% (most grades)
  • Ultra-low P: <0.015% (automotive)
  • Effect: Cold shortness, brittleness
  • Control: Basic slag, lime addition
Sulfur (S)
  • Maximum: 0.050% (most grades)
  • Ultra-low S: <0.015% (deep drawing)
  • Effect: Hot shortness, inclusion formation
  • Control: Desulfurization, Mn addition
⚡ Critical Ratios
  • Mn/S: >20 (preferably >30)
  • C/P: Monitor for cold shortness
  • Si+Al: 0.20-0.60% total deoxidation

⚙️ Charge Mix Optimization Guidelines

🟤 Sponge Iron (DRI)
  • Typical Range: 40-70%
  • Advantages: Low tramp elements, consistent quality
  • Considerations: Higher cost, oxidation losses
  • Metallization: >85% recommended
♻️ Scrap Steel
  • Typical Range: 15-40%
  • Advantages: Lower cost, good yield
  • Risks: Tramp elements (Cu, Sn, Cr)
  • Quality: Use clean, sorted scrap
⚫ Pig Iron
  • Typical Range: 10-30%
  • Function: Carbon source, dilution
  • Benefits: High yield, known chemistry
  • Limit: High Si pig iron increases Si content

🔬 Ferroalloy Addition Strategy

🔹 SiMn (Silico-Manganese)
  • Timing: Primary deoxidation stage
  • Typical Addition: 2-5 kg/ton
  • Recovery: Si: 50-70%, Mn: 85-95%
  • Function: Combined Si-Mn deoxidation
🔸 FeMn (Ferro-Manganese)
  • Timing: Final adjustment stage
  • Typical Addition: 1-3 kg/ton
  • Recovery: Mn: 90-95%
  • Function: Mn adjustment, desulfurization aid
📋 Addition Sequence
  1. 1. Melting: Charge metallic materials
  2. 2. Refining: Slag formation, P removal
  3. 3. Deoxidation: Add SiMn for primary deox
  4. 4. Adjustment: FeMn for final Mn level
  5. 5. Final Deox: Al wire/powder if required
  6. 6. Casting: Temperature and chemistry check

💡 Pro Tip: Always add ferroalloys in small portions to avoid temperature drop and ensure proper mixing.

⚗️ Reduction Reactions & Furnace Chemistry

🔥 Primary Reduction Reactions
Iron Oxide Reduction (DRI/Sponge Iron):
Fe₂O₃ + 3CO → 2Fe + 3CO₂
FeO + CO → Fe + CO₂

Residual oxides in DRI continue reducing in furnace

Silicon Reduction (from SiMn):
SiO₂ + 2C → Si + 2CO
2SiO₂ + Si → 3SiO (volatile)

High temperature reaction, significant Si losses possible

Manganese Reduction:
MnO + C → Mn + CO
MnO₂ + 2C → Mn + 2CO

Better recovery than Si, stable in steel bath

💨 Oxidation & Loss Mechanisms
Carbon Oxidation:
C + ½O₂ → CO
C + CO₂ → 2CO

Primary decarburization mechanism during refining

Silicon Oxidation:
Si + O₂ → SiO₂
2Si + O₂ → 2SiO (gas)

Forms slag, volatile losses at high temp

Iron Oxidation:
2Fe + O₂ → 2FeO
3Fe + 2O₂ → Fe₃O₄

Yield loss, increases slag FeO content

🎯 Your Charge Mix – Expected Reactions
🌡️ Temperature-Dependent Reactions
1400-1500°C (Melting Zone):
  • • DRI residual oxide reduction
  • • Initial carbon dissolution
  • • Slag formation begins
1500-1600°C (Refining Zone):
  • • Active decarburization
  • • Phosphorus removal
  • • Sulfur partition to slag
1600-1700°C (Superheating):
  • • Ferroalloy dissolution
  • • Final deoxidation
  • • Inclusion flotation
⚖️ Equilibrium Considerations
Carbon-Oxygen Equilibrium:

CO formation limits final C content based on temperature and pressure

Deoxidation Equilibrium:

Si, Mn, Al compete for oxygen – addition sequence matters

Slag-Metal Equilibrium:

P, S distribution depends on slag basicity and temperature

🌡️ Critical Process Parameters

Temperature Control
  • Melting: 1580-1620°C
  • Refining: 1600-1650°C
  • Tapping: 1650-1680°C
  • Casting: 1520-1560°C
Slag Management
  • Basicity (CaO/SiO₂): 2.5-3.5
  • FeO Content: <15% for good yield
  • MgO Saturation: 8-12%
  • Fluidity: Maintain proper viscosity

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